Structural and magnetic ordering in Fe6(Ge,Ga)5 intermetallic compounds

Seminars

Frank Laboratory of Neutron Physics

Seminar on the structure and dynamics of crystals

Scientific leader: Anatoly Balagurov

Date and Time: Friday, 20 June 2025, at 11:00 AM

Venue: NICM Conference hall, bld 42а, 3rd floor, Frank Laboratory of Neutron Physics

Seminar topic: “Structural and magnetic ordering in Fe6(Ge,Ga)5 intermetallic compounds”

Speaker: Roman Khalaniya (Moscow State University)

Abstract:

Iron germanides and gallides form a diverse range of compounds with various crystal structures, from ordered solid solutions based on different iron modifications to complex monoclinic structures with numerous crystallographically independent positions. Consequently, these compounds exhibit a wide range of physical properties, including magnetostriction and non-collinear magnetism, as well as the unusual semiconductor-type conductivity characteristic of intermetallides. The presence of the isostructural compounds Fe6Ge5 and a-Fe3Ga, allows us to investigate the influence of the p-element on the structure and magnetic properties of these intermetallides in detail. This study characterises these compounds in detail, obtaining for the first time their derivatives of the general composition Fe6-y(Ge1-xGax)5+y: T1 (x = 0.6-0.9, y = 0) and T2 (x = 0.3-0.6, y = 0-0.12). Their crystal structure and magnetic behaviour are presented and discussed.